Give the method of preparation of ethyne (acetylene) from vicinal dihalides.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Vicinal dihalides are compounds in which two halogen atoms are attached to adjacent carbon atoms.
When vicinal dihalides are treated with alcoholic potassium hydroxide $(KOH)$,they undergo dehydrohalogenation to form vinyl halides,which then react with sodamide $(NaNH_2)$ to form ethyne.
The reaction is as follows:
$CH_2Br-CH_2Br + 2KOH (\text{alc.}) \longrightarrow CH \equiv CH + 2KBr + 2H_2O$
Alternatively,using $NaNH_2$ in liquid ammonia:
$CH_2Br-CH_2Br \xrightarrow{NaNH_2 / liq. NH_3} CH \equiv CH$

Explore More

Similar Questions

Predict the nature of $P$ in the following reaction:
$CH_3-C\equiv C-CH_3 \xrightarrow[heat]{NaNH_2 / \text{inert solvent}} P$

The correct order of acidic nature of the following alkynes is:
$I$. $HC \equiv CH$
$II$. $CH_3-C \equiv C-CH_3$
$III$. $CH_3-C \equiv CH$

Which of the following compounds forms a $Na$-salt upon reaction with $NaNH_2$?

Carbon-carbon bond length is minimum in

Which one is the correct order of acidity?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo